Encyclopedia of Practical Receipts and Processes

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Substitute for Lucifer Matches

The dangers arising from the universal adoption of the common lucifer match have induced chemists to seek a substitute for it. M. Peltzer has recently proposed a compound which is obtained in the shape of a violet powder, by mixing together equal volumes of solutions of sulphate of copper, one of which is supersaturated with ammonia, and the other with hyposulphite of soda. A mixture fresh nor salt water has any injurious effect of chlorate of potash and the above powder on blasting powders; they need only to be dried to regain their explosive character.

Their emitting but little smoke renders them useful in underground operations, and their explosive force is eight times that of gunpowder. They explode with extreme facility, either by contact with a strong acid, a slight elevation of temperature, or the slightest friction. In preparing them, therefore, excessive precaution is necessary, especially in mixing will catch fire by percussion or rubbing; it burns like gunpowder, and leaves a black residue. M. Viederbold proposes a mixture of hyposulphite of lead, or baryta, or chlorate of potash, for matches without phosphorus.

The only inconvenience of this compound is that it attracts moisture too easily.

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