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Spectrum

Collier's New Encyclopedia (1921)

in optics, the colored image or images produced when the rays from any source of light are decomposed or dispersed by refraction through a prism. It has been proved that whiteness is simply a totality of effect produced by the simultaneous effects of many colors falling at once upon the retina. It has been shown (see RE- FRACTION) how a beam of light is deflected on meeting at any inclination the surface of a denser medium, and it is obvious that by using a prism with two inclined surfaces, the beam may be permanently deflected. It is found that each different color, representing a different length of wave, is differently refracted by the prism, or has its own special index of refractions hence the or spreads out, in order, according to their refrangibility, all the different colors of which the beam is composed. This appearance is the spectrum of that particular light. Solids or liquids heated to incandescence-as the particles of soot in a candle flamealways yield an unbroken band of colors shading into one another; this is called a continuance spectrum. Incandescent gases generally yield lines or bands only, and this is a line or banded spectrum. When portions of what would have been a continuous spectrum are intercepted or cut out by an intervening medium this is called an absorption spectrum. Besides the waves of such a length as cause visual effects, there are many more beyond the red at one end of the spectrum and the violet at the other, which produce powerful chemical and heating effects. This portion is sometimes called the invisible spectrum, sometimes described as the ultra-red or ultra-violet spectrum. Its length greatly exceeds that of the visible spectrum, and it is found to comprise lines and bands precisely analogous to those occurring in the luminous portion.

What Has Changed in the Last Century

Collier's in 1921 could describe spectra accurately — continuous, line, banded, absorption — and correctly tie color to wavelength, but it could not say why an incandescent gas emits lines at all. That answer came from quantum theory: Bohr's 1913 atomic model and then the full quantum mechanics of 1925-26 showed each line as an electron jumping between fixed energy levels, making a spectrum a direct fingerprint of atomic structure. The 1921 phrase "invisible spectrum" for the ultra-red and ultra-violet has also gone; the electromagnetic spectrum is now treated as one continuum from radio waves to gamma rays, with the visible band a narrow slice of it. Spectroscopy became astronomy's chief tool — Hubble used spectral redshifts in 1929 to show the universe expanding, and today the same technique identifies gases in the atmospheres of planets orbiting other stars.

Written for this edition, 2026.