Tinning
The Encyclopedia of Founding (1892)
Important: Safety Warning
This page describes trade processes that use dangerously toxic materials such as cyanide solutions, mercury amalgams, or strong acids. These processes require training, equipment, and precautions far beyond what the text describes.
This information has been left in for historical purposes but should not be acted upon.
Brass and copper articles boiled in a solution of stannate of potassa, mixed with turnings of tin, are in a short time covered with a layer of pure tin. If the articles be boiled in caustic alkali or cream of tartar with tin-powder, the same effect is produced; the latter mixture is composed of water 2 pails, cream of tartar 1/2 lb., salt 1/2 pint. Keep the article moving throughout the process. Copper tubes may be tinned inside by a solution of salts of tin added to the solution of Rochelle salts, which forms a precipitate of stannous tartrate, which must be washed and then dissolved in caustic lye. Rinse the copper tube with sulphuric acid, and afterwards wash it well out, after which the tube must be filled with the alkaline solution, slightly warm, and a tin rod inserted; the latter will at once cause a thin coat of metallic tin to be deposited. Iron pots and similar articles are first cleaned by immersion in sulphuric acid and water for new metal, and muriatic acid and water for old metal, with a subsequent scouring with sand, followed by washing in water. They are then put into a bath prepared with cream of tartar 1 ounce, protochloride of tin 1 ounce, water 10 quarts. This bath is kept in a wooden or stone-ware vessel at a temperature of 190 deg. Small pieces of zinc are distributed among the articles in the bath, which may be taken out and washed with water when the coat of tin deposited thereon is thick enough. If iron articles are first cleaned as above, they may be made hot enough to melt tin, and then rubbed with salammoniac, as well as sprinking the latter (in powder) over them; the tin can then be applied, and as it melts be spread evenly all over with a hand-cloth. A cold process of tinning is to blend tin-foil and mercury into a soft, fusible amalgam, and, after cleaning as before directed, rub on the amalgam while the article is moist, and then apply heat to evaporate the mercury. See TIN-PLATE.
What Has Changed in the Last Century
The 1892 Encyclopedia of Founding describes tinning as a workshop craft of hot dips, cream-of-tartar baths and, coldest of all, rubbing on a tin-mercury amalgam and driving off the mercury with heat — a procedure that would now be treated as a serious poisoning hazard and is not used anywhere legitimately. Industrial tinning moved to continuous electrolytic lines from the late 1930s, driven partly by wartime tin shortages; these deposit coatings far thinner and more uniform than any hot dip, which is why virtually all modern "tin cans" are electroplated steel with only a whisper of tin. The chemistry itself has not vanished — immersion and electroless tin still coat circuit boards and copper wire — but the alkaline stannate and stannous chloride baths are now run under controlled conditions with waste treatment, not in a stoneware pot at 190 degrees. Tinned copper cookware, once routine, survives mainly as an artisan speciality, displaced by stainless steel; and tin-lead solder, the other great use of the metal, has been largely legislated out of consumer electronics since the EU's RoHS rules took effect in 2006.
Written for this edition, 2026.